There are 14 words that start with 'effi'.
| effigy | efficacy | 
| effigial | effigies | 
| efficient | efficacies | 
| efficacity | efficiency | 
| efficacious | efficiently | 
| efficacities | efficiencies | 
| efficaciously | efficaciousness | 
Note: These 14 words that start with 'effi' are found from the USA & Canada version of the tournament Scrabble word list.